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Currently, the development of TiO₂ memristors is associated with their use in modern highly technological applications, such as resistive random-access memory (RRAM), biohybrid systems, and sensors, as schematically shown in Figure 1A. In this mini-review, we briefly outline and summarize the key milestone achievements, as well as recent advances in the synthesis, fabrication, and application of TiO₂-based memristors. A special focus is placed on the relationships between the synthesis and deposition methods, the effects of post-synthesis treatment, and the resistive switching properties.

In 1970, Japanese scholars studied the phase diagram of iron oxide microcrystalline formation, which laid a theoretical foundation for the preparation method of iron oxide yellow crystal seed. According to the research results, iron yellow crystal seeds can be formed under acidic or alkaline conditions. Because iron yellow is a crystal structure, in order to crystallize into pigment particles, it must first form crystal nucleus and become crystal seed, and then the crystal nucleus grows into iron yellow. Otherwise, only thin and dim color paste can be obtained, which does not have pigment properties. Acid process can be divided into iron sheet process and drop addition process.